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Line intensities are also governed by symmetry properties of the rotation-vibration states, which may show degeneracies arising froin different orientations of existing nuclear spins For each nucleus with spin quantum number 1,there are 21+ 1 possible orientations of the spin with M I = -I, ._,+I, as discussed before in connection with the rotational quantum number M J Two examples will demonstrate the effects that have to be taken into account In the first category, let us consider nuclei with an integral spin quantum number (eg, D with I = 1, I6O and '*C with I = 0; for the last two nuclei actually no spin function is involved).



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The C02 molecule is said to obey Bose-Einstein statistics, according to which the total wave function approximated by a product of electronic, vibrational, rotational and nuclear spin contributions must be symmetric with respect to the symmetry operation of exchanging nuclei In practically all stable molecules, the electronic and vibrational ground state are totally symmetric It can be shown that the rotational wave functions with even I quantum numbers are also totally symmetric, whereas states with an odd J are antisymmetric In the case of CO2, it can be concluded that only rotational states with even values of J exist in the vibrational ground state This is in contrast to the first excited antisymmetric stretching vibrational state of CO; , where only rotational levels with odd J values exist The line spacings for the P- and R-branches are thus twice as large as those where all rotational states are allowed.





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The n-tiered architecture follows naturally from three-tiered architectures. The n-tiered architecture may add any number of tiers needed to decouple software layers. Decoupling layers provides for better software design. Adding tiers provides more opportunities to decouple software layers and move them from the client to the server. As is shown in Figure 2.4, an n-tiered architecture can be made to more closely match the layers of an application s architecture. In many cases, changes on the server are easier to manage than changes on the client because servers tend to be centralized. A few servers handle many times more clients. Decoupling also offers more opportunities to share components. Threetiered systems make it much easier to share just the business logic between applications. Now, with n-tiered systems, there are many more opportunities to share; it is often even possible to share application logic between applications.

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Besides, in this example the central gap is only half as large as in the more general case, represented by the isotopic 1 8 0 ' 2 C ' 6 0 molecule which lacks a center of symmetry The reader may verify the resulting line pattern of the normal isotope by comparing the rotational level structure and spectrum of CO shown in Fig 43-2 However, with high resolution spectra provided the line density of hot band transitions is twice as high as that of the fundamentals (see Fig 43-6 and Tab 43-5) For the more complicated term scheme and selection rules in these cases, see Allen and Cross (1963) The situation is different for molecules that possess nuclei with half integral spin quantum numbers.

The list of examples includes 'H with 1 = 112 or C1 with 1 = 312, both of which obey Femi-Dirac statistics, which requires that the total molecular eigenfunction be antisymmetric This may be exemplified by the spin statistical weights of the rotational energy levels of C2Hz For the protons in this molecule three symmetric spin functions and one antisymmetric can be formulated, which must be paired with rotational states o appropriate symmetry As a consequence, antisymmetric states with f odd J-quantum numbers are found to be triply degenerate on the premise of a totally symmetric electronic and vibrational state This results in an alternating line intensity in a rotation-vibration band, which may be of valuable assistance for the assignment of rotational quantum numbers, and may provide information about the molecular symmetry..

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